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Issue 2, 1990
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Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones

Abstract

The Me3Si group in β-trimethylsilyl cycloalkanones was able to direct the Norrish type I cleavage by providing regioselectivity in the C-1-C-2 bond cleavage and by increasing the quantum yield and the reaction rate.

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Article type: Paper
DOI: 10.1039/C39900000161
Citation: J. Chem. Soc., Chem. Commun., 1990,0, 161-163
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    Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones

    J. R. Hwu, B. A. Gilbert, L. C. Lin and B. R. Liaw, J. Chem. Soc., Chem. Commun., 1990, 0, 161
    DOI: 10.1039/C39900000161

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