Annulated sugar derivatives with α- and β-allylic alcohol groups have been subjected to the Stork silyl methylene radical cyclisation reaction, in both cases, trans-addition of the radical occurred to produce a new fused ring system.
R. V. Bonnert, M. J. Davies, J. Howarth and P. R. Jenkins, J. Chem. Soc., Chem. Commun., 1990, 148 DOI: 10.1039/C39900000148
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