Asymmetric epoxidation of branched hydroxypropene nucleosides with either (+)- or (–)-diisopropyl tartrate led surprisingly to only one diastereoisomer, whose stereochemistry was determined by comparison with the Darzens products.
M. Bessodes, M. Egron and K. Antonakis, J. Chem. Soc., Perkin Trans. 1, 1989, 2099 DOI: 10.1039/P19890002099
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