Issue 9, 1989
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Unprecedented 1,4-methyl group migration in a rhodium-catalysed hydrosilylation of ketones by 1,2-bis(dimethylsilyl)benzene

Hideo Nagashima,   Kazuo Tatebe  and  Kenji Itoh  

Abstract

A rhodium-catalyzed hydrosilylation of ketones afforded a mixture of alkoxysilanes, 1-(ROSiMe2)-2-(HMe2Si)C6H4 and 1-(ROSiHMe)-2-(Me3Si)C6H4; the latter resulted by 1,4-methyl group migration during the hydrosilylation.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P19890001707
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 1707-1708

Permissions

Request permissions

Unprecedented 1,4-methyl group migration in a rhodium-catalysed hydrosilylation of ketones by 1,2-bis(dimethylsilyl)benzene

H. Nagashima, K. Tatebe and K. Itoh, J. Chem. Soc., Perkin Trans. 1, 1989, 1707 DOI: 10.1039/P19890001707

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements