Issue 9, 1989

Aziridination of phenylalkenylsilanes and phenylalkenylstannanes

Abstract

The phenylalkenylsilanes (8)–(10), phenylalkenylstannanes (11)–(13), and 2-triphenylstannylpropene (14) have been aziridinated using N-acetoxyaminoquinazolone (15). Relative configurational assignments at positions 1 (invertomers), 2, and 3 on the aziridine ring have been made which suggest that an attractive interaction is present between the quinazolone ring carbonyl oxygen and the tin atom in the aziridines (4)–(7).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 1657-1661

Aziridination of phenylalkenylsilanes and phenylalkenylstannanes

R. S. Atkinson and B. J. Kelly, J. Chem. Soc., Perkin Trans. 1, 1989, 1657 DOI: 10.1039/P19890001657

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