Novel azamacrocycles having amide-functionalized arm groups have been shown to mediate selective and efficient transport of ‘hard’ alkali and alkaline earth metal cations via three-dimensional complexations, while the parent azamacrocycles favour ‘soft’ metal cations.
H. Tsukube, H. Adachi and S. Morosawa, J. Chem. Soc., Perkin Trans. 1, 1989, 1537 DOI: 10.1039/P19890001537
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