SCHEDULED MAINTENANCE
Mild thermal fragmentation of 2-azido-1-methylindole and 2-azidobenzo[b]furan leads to an ortho-quinoidal enimine or enone intermediate respectively through a ring-cleavage reaction of the corresponding nitrene.
E. Foresti, P. Spagnolo and P. Zanirato, J. Chem. Soc., Perkin Trans. 1, 1989, 1354 DOI: 10.1039/P19890001354
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