A number of β-C-glucopyranosides having an activated methylene or methine group bonded to the anomeric carbon are obtainable in quantitative yield from the corresponding α-isomers by simple equilibration catalysed by various bases at room temperature.
P. Allevi, M. Anastasia, P. Ciuffreda, A. Fiecchi and A. Scala, J. Chem. Soc., Perkin Trans. 1, 1989, 1275 DOI: 10.1039/P19890001275
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