In situ trapping of lithiated phthalocyanines by chlorotrimethylsilane produces highly soluble phthalocyanines; the reaction is regiospecific and yields non-peripherally (1, 4, 8, 11, 15, 18, 22, and 25 positions) substituted phthalocyanines, H2Pc(SiMe3)x where x= 4, 3, and 2.
M. J. Chen, C. M. Fendrick, R. A. Watson, K. S. Kinter and J. W. Rathke, J. Chem. Soc., Perkin Trans. 1, 1989, 1071 DOI: 10.1039/P19890001071
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