SCHEDULED MAINTENANCE
[13C2H]-Labelled cycloartenol (2) was isolated from cultured cells of Physalis peruviana fed with [2-13C2H3]acetate. The distribution of the deuterium atoms was determined by 13C-{1H}{2H} n.m.r. spectroscopy. The 1,2-hydride migrations (20-H from C-17, 17-H from C-13, and 8-H from C-9) were verified in the biosynthesis of cycloartenol (2).
S. Seo, A. Uomori, Y. Yoshimura, K. Takeda, H. Seto, Y. Ebizuka, H. Noguchi and U. Sankawa, J. Chem. Soc., Perkin Trans. 1, 1989, 261 DOI: 10.1039/P19890000261
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