SCHEDULED MAINTENANCE
1,2,3,4-Tetrahydroquinoline and Indoline as their lithium carbamates undergo α-metallation with a ButLi–KOBut mixture. The resulting α-metallo species react with carbonyl electrophiles to give the α-alkylated secondary amines in an overall one-pot procedure.
A. R. Katritzky and S. Sengupta, J. Chem. Soc., Perkin Trans. 1, 1989, 17 DOI: 10.1039/P19890000017
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