The reaction between iron(III) and thiocyanate ions has been studied in several electrolyte solutions over the concentration range 0–6 mol dm–3. The observed positive kinetic salt effects may be interpreted as arising as a result of ion–solvent interactions. Support for these conclusions comes from an examination of the activity coefficients of species estimated from the treatment given by Pitzer.
M. J. Capitán, E. Muñoz, M. M. Graciani, R. Jiménez, I. Tejera and F. Sánchez, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 4193 DOI: 10.1039/F19898504193
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...