Homobinuclear chelate complexes of the 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine anion radical ligand with the metal fragments [Os(bpy)]2+(d6), [Rh(norbonadiene)]+(d8) and [Au(PPh3)]+(d10) have been studied by ESR spectroscopy. The unique suitability of this radical ligand for coordination of heavy metal fragments and for ESR investigations is discussed.
S. Kohlmann, V. Kasack, E. Roth and W. Kaim, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 4047 DOI: 10.1039/F19898504047
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