Issue 12, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

On the existence of the anion trichloro(η-cyclopentadienyl)titanate(1–). Crystal structure of the salt [Co(C5H5)2][Ti(C5H5)Cl3]

David L. Hughes,   Manuel Jimenez-Tenorio  and  G. Jeffery Leigh  

Abstract

We have isolated, and characterised by elemental and X-ray crystal structure analysis, and e.s.r. and n.m.r. spectroscopy, the salt [Co(C5H5)2][Ti(C5H5)Cl3]. The results show that the ion [Ti(C5H5)Cl3]– is a stable species of not unexpected properties, despite an earlier report that it readily loses chloride. This represents the first structural analysis of a (cyclopentadienyl)trihalogenotitanate(1–) species.

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Article information

DOI
https://doi.org/10.1039/DT9890002453
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 2453-2455

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On the existence of the anion trichloro(η-cyclopentadienyl)titanate(1–). Crystal structure of the salt [Co(C5H5)2][Ti(C5H5)Cl3]

D. L. Hughes, M. Jimenez-Tenorio and G. J. Leigh, J. Chem. Soc., Dalton Trans., 1989, 2453 DOI: 10.1039/DT9890002453

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