Issue 12, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactions of 1-alkynes with trans-[ReCl(N2)(Ph2PCH2CH2PPh2)2]: preparation of the vinylidene compounds trans-[ReCl([double bond, length half m-dash]C[double bond, length half m-dash]CHR)(Ph2PCH2CH2PPh2)2](R = alkyl or aryl) and X-ray structure of trans-[ReCl([double bond, length half m-dash]C[double bond, length half m-dash]CHPh)(Ph2PCH2CH2PPh2)2]

Armando J. L. Pombeiro,   Sílvia S. P. R. Almeida,   M. Fátima C. G. Silva,   John C. Jeffrey  and  Raymond L. Richards  

Abstract

The vinylidene complexes trans-[ReCl([double bond, length half m-dash]C[double bond, length half m-dash]CHR)(dppe)2](1; R = Ph, Et, But, SiMe3, CO2Me, CO2Et, or C6H10OH-1; dppe = Ph2PCH2CH2PPh2) have been prepared by reaction of trans-[ReCl(N2)(dppe)2] with an excess of the appropriate 1-alkyne (HC[triple bond, length half m-dash]CR), in refluxing tetrahydrofuran (thf) or under tungsten-filament light (in thf or toluene). The X-ray structural analysis of (1; R = Ph) has been performed.

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Article information

DOI
https://doi.org/10.1039/DT9890002381
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 2381-2387

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Reactions of 1-alkynes with trans-[ReCl(N2)(Ph2PCH2CH2PPh2)2]: preparation of the vinylidene compounds trans-[ReCl([double bond, length half m-dash]C[double bond, length half m-dash]CHR)(Ph2PCH2CH2PPh2)2](R = alkyl or aryl) and X-ray structure of trans-[ReCl([double bond, length half m-dash]C[double bond, length half m-dash]CHPh)(Ph2PCH2CH2PPh2)2]

A. J. L. Pombeiro, S. S. P. R. Almeida, M. F. C. G. Silva, J. C. Jeffrey and R. L. Richards, J. Chem. Soc., Dalton Trans., 1989, 2381 DOI: 10.1039/DT9890002381

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