Issue 6, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis of ammonium ions and nitrosylation reactions using nitrosyl chloride and alkyl nitrites

M. Ishaque Khan  and  U. C. Agarwala  

Abstract

Nitrosyl chloride (NOCl) reacts with RuCl3·xH2O in the presence of PPh3 in different alcohols leading to the formation of ammonium ions and [Ru(NO)Cl3(PPh3)2] under mild experimental conditions, through reductive deoxygenation. Some parameters affecting the reactivity of the redox system have been qualitatively defined. Similar reactions in tetrahydrofuran do not yield [NH4]+ ions. Alkyl nitrites (RONO, R = Me or Et) have also been successfully employed as nitrosylating agents for the syntheses of nitrosyl complexes of RuII, RuIII, RhI, and IrI.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9890001139
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 1139-1142

Permissions

Request permissions

Synthesis of ammonium ions and nitrosylation reactions using nitrosyl chloride and alkyl nitrites

M. I. Khan and U. C. Agarwala, J. Chem. Soc., Dalton Trans., 1989, 1139 DOI: 10.1039/DT9890001139

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements