Issue 6, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

Monohydrido-bridged platinum(II)–gold(I) complexes. X-Ray crystal structure of [(Ph3P)2(C6Cl5)Pt(µ-H)Au(PPh3)]ClO4·2Et2O

Margarita Crespo,   Joaquim Sales  and  Xavier Solans  

Abstract

The compounds [(Ph3P)2RPt(µ-H)Au(PPh3)]ClO4(R = C6Cl5, C6H3Cl2-2,5, or C6H4Cl-p) have been obtained by reaction of the corresponding complex trans-[PtH(R)(PPh3)2] with [Au(thf)(PPh3)]ClO4 and they have been characterized by 1H and 31P n.m.r. spectroscopy. The molecular structure of [(Ph3P)2(C6Cl5)Pt(µ-H)Au(PPh3)]ClO4 has been determined by a single-crystal X-ray structural analysis. The crystals are triclinic, space group P1, with a= 22.866(7), b= 13.844(5), c= 11.392(4)Å, α= 110.79(3), β= 85.13(2), γ= 96.95(2)°, and Z= 2.

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Article information

DOI
https://doi.org/10.1039/DT9890001089
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 1089-1092

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Monohydrido-bridged platinum(II)–gold(I) complexes. X-Ray crystal structure of [(Ph3P)2(C6Cl5)Pt(µ-H)Au(PPh3)]ClO4·2Et2O

M. Crespo, J. Sales and X. Solans, J. Chem. Soc., Dalton Trans., 1989, 1089 DOI: 10.1039/DT9890001089

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