Issue 5, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

Gas-phase molecular structure of NN′-bis(trimethylsilyl)sulphur di-imide, determined by electron diffraction

David G. Anderson,   Heather E. Robertson,   D. W. H. Rankin  and  J. Derek Woollins  

Abstract

The molecular geometry of Me3SiNSNSiMe3in the gas phase has been studied by electron diffraction. The molecule has C2 symmetry with a distorted syn,syn conformation. Principal parameters are: ra(S[double bond, length half m-dash]N) 153.6(3), ra(Si–N) 173.8(3), and ra(Si–C) 186.9(1) pm; NSN 129.5(16), SNSi 132.9(7), and SN twist (relative to syn,syn conformation) 42(1)°.

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Article information

DOI
https://doi.org/10.1039/DT9890000859
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 859-862

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Gas-phase molecular structure of NN′-bis(trimethylsilyl)sulphur di-imide, determined by electron diffraction

D. G. Anderson, H. E. Robertson, D. W. H. Rankin and J. D. Woollins, J. Chem. Soc., Dalton Trans., 1989, 859 DOI: 10.1039/DT9890000859

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