Issue 3, 1989

Thiolate complexes of osmium(III) with tertiary phosphines and their dicarbonyl derivatives of osmium(II): X-ray crystal structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2]

Abstract

The preparation and physical properties of complexes of the type [Os(SC6F5)3(PR3)2] and [Os(SC6F5)2(CO)2(PR3)2](PR3= PMe2Ph, PMePh2, PEt2Ph, or PEtPh2), and the X-ray structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2] are described.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 419-423

Thiolate complexes of osmium(III) with tertiary phosphines and their dicarbonyl derivatives of osmium(II): X-ray crystal structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2]

D. Cruz-Garritz, P. Sosa, H. Torrens, A. Hills, D. L. Hughes and R. L. Richards, J. Chem. Soc., Dalton Trans., 1989, 419 DOI: 10.1039/DT9890000419

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