Issue 1, 1989
From the journal:

Journal of the Chemical Society, Dalton Transactions

Comparison of the structures and properties of [N(C2H5)4][Pt{{S2C2(CN)2}2] and [H3O]x[NH4]1–x[Pt{S2C2(CN)2}2]·2 –xH2O

Peter I. Clemenson,   Allan E. Underhill,   Michael B. Hursthouse  and  Richard L. Short  

Abstract

The crystal structures of [N(C2H5)4][Pt{S2C2(CN)2}2] and [H2O]x[NH4]1–x[Pt{S2C2(CN)2}2]·2 –xH2O are described. Both compounds contain anion dimers. In the former the dimer has a slipped configuration with Pt ⋯ S interactions whereas the latter contains the anions in an eclipsed configuration with a Pt over Pt arrangement. The difference in the structures is related to the size and nature of the cation. The electrical conduction and magnetic properties are related to the structures.

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Article information

DOI
https://doi.org/10.1039/DT9890000061
Article type
Paper

J. Chem. Soc., Dalton Trans., 1989, 61-65

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Comparison of the structures and properties of [N(C2H5)4][Pt{{S2C2(CN)2}2] and [H3O]x[NH4]1–x[Pt{S2C2(CN)2}2]·2 –xH2O

P. I. Clemenson, A. E. Underhill, M. B. Hursthouse and R. L. Short, J. Chem. Soc., Dalton Trans., 1989, 61 DOI: 10.1039/DT9890000061

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