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Issue 24, 1989
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Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

Abstract

UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the µ-dinitrogen complex has been determined and the Os–N(N2) distances found to be 1.873(9) and 1.893(9)Å.

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Article type: Paper
DOI: 10.1039/C39890001883
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 1883-1884
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    Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

    C. Che, H. Lam, W. Tong, T. Lai and T. Lau, J. Chem. Soc., Chem. Commun., 1989, 0, 1883
    DOI: 10.1039/C39890001883

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