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Issue 21, 1989
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The tetranuclear cluster FeIII[FeIII(salicylhydroximato)(MeOH)(acetate)]3 is an analogue of M3+(9-crown-3)

Abstract

The first example of transition metal co-ordination to ethereal like oxygens of a 9-metallocrown-3 ether is seen in FeIII[FeIII(salicylhydroximato)(MeOH)(acetate)]3 and leads to an unusual tetranuclear cluster which exhibits both inter- and intra-cluster antiferromagnetic interactions and an S= 5 ground state.

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Article type: Paper
DOI: 10.1039/C39890001606
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 1606-1608
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    The tetranuclear cluster FeIII[FeIII(salicylhydroximato)(MeOH)(acetate)]3 is an analogue of M3+(9-crown-3)

    M. S. Lah, M. L. Kirk, W. Hatfield and V. L. Pecoraro, J. Chem. Soc., Chem. Commun., 1989, 0, 1606
    DOI: 10.1039/C39890001606

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