Issue 24, 1989

The reaction of chiral nucleophiles with organomanganese arene complexes

Abstract

The reaction of the enolate derived from chiral N-acyloxazolidinone (1) and organomanganese arene complexes (2) gives η5-dienyl complexes (3) which can be converted into chiral 2-arylpropionic acids by cleavage of the chiral auxiliary and oxidation of the η5-dienyl moiety.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1897-1899

The reaction of chiral nucleophiles with organomanganese arene complexes

W. H. Miles, P. M. Smiley and H. R. Brinkman, J. Chem. Soc., Chem. Commun., 1989, 1897 DOI: 10.1039/C39890001897

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