Issue 24, 1989

Baeyer–Villiger oxidation of bicycloheptanone to cyclopentapyranone: a novel synthesis of iridomyrmecin, isoiridomyrmecin, and boschnialactone

Abstract

Stereocontrolled syntheses of iridomyrmecin, isoiridomyrmecin, and boschnialactone are accomplished through a Baeyer–Villiger oxidation and either a cuprate coupling reaction or catalytic hydrogenation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1876-1878

Baeyer–Villiger oxidation of bicycloheptanone to cyclopentapyranone: a novel synthesis of iridomyrmecin, isoiridomyrmecin, and boschnialactone

T. Wang and C. Yang, J. Chem. Soc., Chem. Commun., 1989, 1876 DOI: 10.1039/C39890001876

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