Issue 23, 1989

Reaction of copper(I) phenoxide with PhNCS: formation and X-ray structure of a novel copper(I) hexameric complex

Abstract

In the presence of phosphites, PhNCS inserts into the Cu1–OPh bond; the complex formed loses the phosphite and oligomerises to form a unique copper(I) hexamer hexakis[µ-{N-phenylimino(p-tolyloxy)methanethiolato} copper(I)](2), as evidenced from an X-ray crystallographic study.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1803-1804

Reaction of copper(I) phenoxide with PhNCS: formation and X-ray structure of a novel copper(I) hexameric complex

N. Narasimhamurthy, A. G. Samuelson and H. Manohar, J. Chem. Soc., Chem. Commun., 1989, 1803 DOI: 10.1039/C39890001803

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