Charge distribution in two monocationic bimetallic organoiron complexes, prepared by transfer of Fp+ to Fp acyl and vinyl species [Fp = Fe(CO)2(C5H5)], have been studied by 57Fe Mössbauer spectroscopy, demonstrating that a considerable degree of polarisation is present in linear organic π-systems interposed between organometallic donor and acceptor groups.
M. R. J. Piper, G. R. Stephenson, R. J. K. Taylor, C. Breen, J. S. Brooks and G. L. Williams, J. Chem. Soc., Chem. Commun., 1989, 1798 DOI: 10.1039/C39890001798
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