Issue 21, 1989

Five-co-ordinate methylmercury and trimethyltin palladium and platinum complexes. X-Ray crystal structure of [N(CH2CH2PPh2)3Pt(HgMe)]BPh4

Abstract

The Pd0 three-co-ordinate (np3)Pd, [np3= N(CH2CH2PPh2)3], and the Pt0 pseudotetrahedral (np3)Pt(PPh3) complexes react with MeHgl and Me3SnCI to give [(np3)M(HgMe)]+ and [(np3)M(SnMe3)]+ complexes; the molecular structure of [(np3)Pt(HgMe)]BPh4 has been established by single crystal diffraction methods.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1686-1688

Five-co-ordinate methylmercury and trimethyltin palladium and platinum complexes. X-Ray crystal structure of [N(CH2CH2PPh2)3Pt(HgMe)]BPh4

C. A. Ghilardi, S. Midollini, S. Moneti, A. Orlandini, G. Scapacci and D. Dakternieks, J. Chem. Soc., Chem. Commun., 1989, 1686 DOI: 10.1039/C39890001686

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