The first asymmetric synthesis of (–)-γ-rhodomycinone (1a) was achieved through a novel regioselective coupling reaction of the chiral AB-(2) and CD-building blocks (3).
H. Fujioka, H. Yamamoto, H. Kondo, H. Annoura and Y. Kita, J. Chem. Soc., Chem. Commun., 1989, 1509 DOI: 10.1039/C39890001509
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