Using a methodology involving consecutive iron-induced C–C and C–N bond formation we have completed the total synthesis of the antibiotic carbazomycin B; application of a novel iron-mediated direct iminoquinone cyclization provides carbazomycin A in an improved high yield sequence.
H. Knölker and M. Bauermeister, J. Chem. Soc., Chem. Commun., 1989, 1468 DOI: 10.1039/C39890001468
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