In a novel reaction, condensing SiO gas attacks toluene very efficiently in the presence of iodine at –90 °C to give a polysiloxane oil with 2- and 4-C6H4CH3, I and H as substituents; oily polyiodosiloxanes are made from SiO and I2 in iodoethane solution at –110 °C.
W. N. Rowlands and P. L. Timms, J. Chem. Soc., Chem. Commun., 1989, 1432 DOI: 10.1039/C39890001432
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