Reaction of secondary allyl vinyl ether with ThexBH2(Thex = 1,1,2-trimethylpropyl) followed by treatment with alkaline hydrogen peroxide gave the corresponding 1,3-diol with high syn selectivity (>16 : 1) with respect to the pre-existing stereogenic centre and the adjacent one.
T. Harada, Y. Matsuda, J. Uchimura and A. Oku, J. Chem. Soc., Chem. Commun., 1989, 1429 DOI: 10.1039/C39890001429
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