Treatment of VOCl42– with tca–(tca–= thiophene-2-carboxylate) under aerobic conditions leads to formation of [V5O9Cl(tca)4]2–, whereas if AgNO3 is also present, the product is [V4O8(NO3)(tca)4]2–; the two anions have been isolated as NR4+ salts and their unusual structures elucidated by crystallographic methods.
D. D. Heinrich, K. Folting, W. E. Streib, J. C. Huffman and G. Christou, J. Chem. Soc., Chem. Commun., 1989, 1411 DOI: 10.1039/C39890001411
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