Addition of a sodium cation to silica-supported Rh, Pd, Pt, and Ni catalysts markedly lowers the activation energy of the hydroformylation process without affecting the regioselectivity of the products and facilitates the CO insertion into propyl intermediates.
S. Naito and M. Tanimoto, J. Chem. Soc., Chem. Commun., 1989, 1403 DOI: 10.1039/C39890001403
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