Issue 18, 1989

Terminal substitution and cage incorporation of an η-cyclopentadienyl ring into borane cage structures; crystal structures of [Mo (η-C5H5)(η51-C5H4)B4H7] and [Mo(η-C5H5)(η32-C3H3)C2B9H9]

Abstract

The synthesis and crystal structure of the molybdaborane [Mo(η-C5H5)(η51-C 5H4)B4H7](1) and of the molybdacarbaborane [Mo(η-C5H5)(η32-C3H3)C2B9H9](2) formed via cyclopentadienyl ring activation are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1397-1399

Terminal substitution and cage incorporation of an η-cyclopentadienyl ring into borane cage structures; crystal structures of [Mo (η-C5H5)(η51-C5H4)B4H7] and [Mo(η-C5H5)(η32-C3H3)C2B9H9]

P. D. Grebenik, M. L. H. Green, M. A. Kelland, J. B. Leach and P. Mountford, J. Chem. Soc., Chem. Commun., 1989, 1397 DOI: 10.1039/C39890001397

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