The Lewis acid mediated reaction of acyliminium ions (6) with γ-oxygen substituted allyltin (1c) gave the amino alcohol derivatives (7) and/or (8) in good yields; in certain cases very high diastereoselectivity was achieved and the procedure was applied to the synthesis of (±)-statine.
Y. Yamamoto and M. Schmid, J. Chem. Soc., Chem. Commun., 1989, 1310 DOI: 10.1039/C39890001310
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