The tricycle (5) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels–Alder (IMDA) reaction; the stereochemistry was established by an X-ray study.
T. K. M. Shing, Y. Tang and J. F. Malone, J. Chem. Soc., Chem. Commun., 1989, 1294 DOI: 10.1039/C39890001294
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...