SCHEDULED MAINTENANCE:
The iridium complex {H2[graphic omitted]H2Me][(P)–NMe2]}[(P)–NMe2=o-(diphenylphosphino)-N,N-dimethyl aniline] formed by intramolecular C-H oxidative addition, as shown by X-ray analysis, behaves as a chemoselective catalyst in hydrogen transfer reduction of α,β-unsaturated ketones to unsaturated alcohols.
E. Farnetti, G. Nardin and M. Graziani, J. Chem. Soc., Chem. Commun., 1989, 1264 DOI: 10.1039/C39890001264
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