Mild methods are developed for the predominant generation of D-pyrrocorphins from 20-methyldihydroisobacteriochlorins carrying ester side chains; the corresponding zinc(II) 20-methyl-D-pyrrocorphinates undergo methylation preferentially at C-17.
C. L. Gibson and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1989, 1223 DOI: 10.1039/C39890001223
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