Cluster molecules, HRu10C(CO)24–, are characterised by interstitial hydride ligands down to 250 K, but below that temperature, progressively more and more molecules acquire externally-bound hydrogens.
P. J. Bailey and M. J. Duer, J. Chem. Soc., Chem. Commun., 1989, 1139 DOI: 10.1039/C39890001139
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