The selectivity of propane carbonylation in HF–SbF5 is found to depend on the propane/CO ratio, and is rationalized in terms of two competing activation processes for the alkane.
S. Delavarenne, M. Simon, M. Fauconet and J. Sommer, J. Chem. Soc., Chem. Commun., 1989, 1049 DOI: 10.1039/C39890001049
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