Cluster synthesis using a methoxymethylidyne template
Abstract
H2Ru3(CO)9(µ3-COMe){Rh(CO)2PPh3} rearranges with loss of CO to form H2Ru3Rh(CO)10PPh3(µ-COMe) from which the Me group can be abstracted thus forming [H2Ru3Rh(CO)11PPh3]–.
H2Ru3(CO)9(µ3-COMe){Rh(CO)2PPh3} rearranges with loss of CO to form H2Ru3Rh(CO)10PPh3(µ-COMe) from which the Me group can be abstracted thus forming [H2Ru3Rh(CO)11PPh3]–.
J. Evans, P. M. Stroud and M. Webster, J. Chem. Soc., Chem. Commun., 1989, 1029 DOI: 10.1039/C39890001029
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