Glucals have been reacted with the naphthylsulphenate ester of 2-hydroxytetralone to afford 2-thio-β-glycosides, which are treated with Raney Ni to produce 2-deoxy-β-glycosides as models for the aureolic acid antibiotics.
S. Ramesh and R. W. Franck, J. Chem. Soc., Chem. Commun., 1989, 960 DOI: 10.1039/C39890000960
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