Issue 14, 1989

Synthesis of the esperamicin A1/calicheamicin γ-trisulphide functionality: thermal stability and reduction

Abstract

The bridgehead enone (16) was converted into the allylic trisulphide (22)/(23) in a completely stereospecific manner, and the thermal and reduction chemistry of some allylic trisulphides was examined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 916-919

Synthesis of the esperamicin A1/calicheamicin γ-trisulphide functionality: thermal stability and reduction

P. Magnus, R. T. Lewis and F. Bennett, J. Chem. Soc., Chem. Commun., 1989, 916 DOI: 10.1039/C39890000916

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