Issue 13, 1989

Electrochemical synthesis and structure of the first example of a ferrocene dication: propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

Abstract

The permethylferrocenophane [(pdmcp)Fe][pdmcp =η55-C5Me4(CH2)3C5Me4] and its oxidised species, monocation and dication salts, were synthesised, in which the latter, [(pdmcp)Fe(NCMe)](PF6)2, has a substantially bent bis(cyclopentadienyl) moiety to accommodate one molecule of MeCN.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 828-829

Electrochemical synthesis and structure of the first example of a ferrocene dication: propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

H. Ogino, H. Tobita, H. Habazaki and M. Shimoi, J. Chem. Soc., Chem. Commun., 1989, 828 DOI: 10.1039/C39890000828

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