Issue 12, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

A new chelating ligand: co-ordination chemistry of [W(CO)(Ph2PC[triple bond, length half m-dash]CPPh2)(S2CNEt2)2]

Thomas M. Nickel,   Simon Y. W. Yau  and  Michael J. Went  

Abstract

The adoption of a cis-bent structure by bis(diphenylphosphino)acetylene (dppa) in [W(CO)(dppa)(S2CNEt2)2] facilitates the formation of [(Et2NCS2)2(OC)W(µ-dppa)Co2(µ-CO)2(CO)4], in which the dppa moiety bridges a cobalt–cobalt bond, and [(Et2NCS2)2(OC)W(µ-dppa)Mo(CO)4], in which the dppa moiety is chelated to a molybdenum centre.

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Article information

DOI
https://doi.org/10.1039/C39890000775
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 775-776

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A new chelating ligand: co-ordination chemistry of [W(CO)(Ph2PC[triple bond, length half m-dash]CPPh2)(S2CNEt2)2]

T. M. Nickel, S. Y. W. Yau and M. J. Went, J. Chem. Soc., Chem. Commun., 1989, 775 DOI: 10.1039/C39890000775

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