The stereochemical requirements for the conversion of tripeptides with unsaturated amino acids in the C-terminal position to bicyclic β-lactam products using isopenicillin N synthase was investigated using the diastereoisomeric peptides (7) and (12).
J. E. Baldwin, R. M. Adlington, C. J. Schofield and H. Ting, J. Chem. Soc., Chem. Commun., 1989, 758 DOI: 10.1039/C39890000758
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