Upon reaction with oct-1-yne, pentacarbonyl[allylamino(2-methoxyphenyl)methylene]chromium undergoes a regio- and diastereo-selective carbene annulation leading finally to a syn-tricarbonyl(3-hexyl-7-methoxy-indanone)chromium complex, the crystal structure of which has been established by X-ray analysis.
K. H. Dötz, H. Erben and K. Harms, J. Chem. Soc., Chem. Commun., 1989, 692 DOI: 10.1039/C39890000692
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