Issue 11, 1989

A rapid and efficient synthesis of 1,2-trans-β-linked glycosides via benzyl- or benzoyl-protected glycopyranosyl phosphates

Abstract

A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl triflate (TMSOTf).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 685-687

A rapid and efficient synthesis of 1,2-trans-β-linked glycosides via benzyl- or benzoyl-protected glycopyranosyl phosphates

S. Hashimoto, T. Honda and S. Ikegami, J. Chem. Soc., Chem. Commun., 1989, 685 DOI: 10.1039/C39890000685

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