The Me3N generated in the carbonyl labilising reaction of Me3NO with [Mn(η6-C6R6)(CO)3]PF6(R = H, Me) deprotonates the subsequently co-ordinated thiophenol affording the novel neutral complexes [Mn(η6-C6R6)(CO)2SPh].
S. Lotz and M. Schindehutte, J. Chem. Soc., Chem. Commun., 1989, 673 DOI: 10.1039/C39890000673
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