Electrophiles and most nucleophiles react with tricyclo[3.2.0.01,4]heptan-2-ones with preferential cleavage of the C(1)–C(4) or C(1)-C(5) bond; X-ray data show the highly strained tricycloheptanone (14) has a bond angle of 149.2(9)° at a tetravalent carbon atom.
H. Finch, R. M. Highcock, S. M. Roberts, K. M. Short and V. Sik, J. Chem. Soc., Chem. Commun., 1989, 670 DOI: 10.1039/C39890000670
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